rare earth nuclei

Four binuclear rare earth complexes [Y2(p-MBA)6(Phen)2] (1), [Y2(p-ClBA)6(Phen)2] (2), [Pr2(BA)6(Phen)2] (3) and [Pr2( p-ClBA)6(H2O)2(Phen)2] (4) [Phen=o-Phenanthroline, p-MBA=4-Methylbenzoic acid, BA=Benzoic acid, p-ClBA =p-Chlorobenzoic acid] were synthesized with hydrothermal reaction.

本文采用水热法合成了4种双核稀土配合物[Y2(p-MBA)6(Phen)2](1)、[Y2(p-ClBA)6(Phen)2](2)、[Pr2(BA)6(Phen)2](3)和[Pr2(p-ClBA)6(H2O)2(Phen)2](4)[Phen=邻菲咯啉、p-MBA=对甲基苯甲酸、BA=苯甲酸、p-ClBA=对氯苯甲酸]。